Product ID:EASTMAN MPK (METHYL PROPYL KETONE)
MSDS Date:01/20/1999
FSC:6810
NIIN:01-459-1994
MSDS Number: CJKXV

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 1-800-EASTMAN

Info Phone: 615-229-6094/2000

Preparer: EASTMAN PRODUCT SAFETY/ST

Cage: 74364

INDUSTRIAL CHEMICAL COMMODITIES INC

ROCKVILLE, MD 20855 US

Telephone: 800-284-5279

Cage: 1ELU0

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Explanation of Carcinogenicity:NOT LISTED.
Effects of Overexposure:INHALATION: HIGH VAPOR CONCENTRATIONS MAY CAUSE
DROWSINESS AND IRRITATION. EYE: HIGH VAPOR CONCENTRATIONS MAY CAUSE
IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL
OR COMMERCIAL HAN DLING BY TRAINED PERSONNEL. INGESTION: EXPECTED
TO BE A LOW INGESTION HAZARD.

First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IN CASE OF IRRITATION
FROM AIRBORNE EXPOSURE, MOVE TO FRESH AIR. IF EASY TO DO, REMOVE
CONTACT LE NSES. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: SEEK MEDICAL ADVICE.

Flash Point Method:TCC
Flash Point:=8.C, 46.4F
Autoignition Temp:=448.C, 838.4F
Lower Limits:(93F):1.56%
Upper Limits:(144F):8.7%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2),
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. WATER MAY BE INEFFECTIVE IN FIGHTING THE FIRE.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPORS MAY CAUSE A FLASH FIRE
OR IGNITE EXPLOSIVELY. VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION AND FLASH BACK. PREVENT BUILDUP OF VAPORS OR
GASES TO EXPLOSIVE CONCENTR ATIONS. MAY FORM PEROXIDES OF UNKNOWN
STABILITY.

Spill Release Procedures:USE PERSONAL PROTECTIVE EQUIPMENT. ELIMINATESE
ALL IGNITION SOURCES. ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. FOR LARGE
SPILLS: USE WATER SP RAY TO DISPERSE VAPORS AND DILUTE SPILL TO A
NONFLAMMABLE MIXTURE. PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS,
OR STREAMS.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINER IN A WELL-VENTILATED PLACE. STORE AWAY FROM HEAT AND
LIGHT.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN: ORGANIC VAPOR. IF RESPIRATORS ARE USED, A
PROGRAM SHOULD BE INST ITUTED TO ASSURE COMPLIANCE WITH OSHA
STANDARD 63 FR 1152, JAN 8, 1998.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE
SKIN CONTACT.
Eye Protection:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE
CONTACT.
Other Protective Equipment:EYE BATH, WASHING FACILITIES.
Supplemental Safety and Health
PRODUCT ID NUMBER: SPC 19010. **VENTILATION: USE PROCESS ENCLOSURES,
LOCAL EXHAUST, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.

HCC:F2
Boiling Pt:=100.6C, 213.F
Melt/Freeze Pt:=-77.8C, -108.F
Vapor Pres:AT20C (68F)37BAR(27.8MMHG
Vapor Density:(AIR=1)2.9
Spec Gravity:AT 20C (68F)(H20=1):0.81
Evaporation Rate & Reference:(N-BUTYL ACETATE=1):2.3
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS LIQUID - KETONE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
MATERIAL CAN REACT VIOLENTLY WITH STRONG BASES, STRONG OXIDIZING
AGENTS, STRONG REDUCING AGENTS.
Stability Condition to Avoid:STABILITY: NORMALLY STABLE; HOWEVER, ON
LONG TERM STORAGE, MATERIALS CONTAINING SIMILAR FUNCTIONAL GROUPS
FORM PEROXIDES OF UNKNOWN STABILITY.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. MIX WITH COMPATIBLE CHEMICAL
WHICH IS LESS FALMMABLE AND INCINERATE. SINCE EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUE , FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER
IS EMPTIED. RESIDUAL VAPORS MAY EXPLODE ON IGNITION; DO NOT CUT,
DRILL, GRIND/WELD ON OR NEAR CONTAINER.

Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: BASED ON ANIMAL
DATA & STRUCTURE-ACTIVITY RELATIONSHIP, THIS PEODUCT IS NOT
EXPECTED TO CAUSE CENTRAL NERVOUS SYSTEM DAMAGE. ACUTE TOXICITY
DATA: DATA FOR METHYL PROPYL K RTONE: ORAL LD-50(RAT): 3.73 G/KG.
INHALATION LC-50 (RAT): >2000 PPM/4 HOURS. DERMAL LD-50 (RABBIT): 8
ML/KG. SUBCHRONIC TOXICITY DATA FOR METHYL PROPYL KETONE:
NO-OBSERVED-EFFECT LEVEL (NOEL) FOR NEU ROTOXICITY = 305 PPM (ONLY
CONCENTRATION TESTED). ORAL STUDY (10 MONTHS, RAT):
LOWEST-OBSERVED-EFFECT LEVEL (LOEL) = 1% IN DRINKING WATER (REDUCED
BODY WEIGHT GAIN); NOEL = 0.5% IN DRINKING WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:SUMMARY: DATA FOR THE MAJOR COMPONENT OF THIS MATERIAL HAVE
BEEN USED TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL. IT
HAS THE FOLLOWING PROPERTIES: A HIGH BIOCHEMICAL OXYGEN DEMAND AND
A POT ENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A LOW
POTENTIAL TO AFFECT AQUATIC ORGANISMS, A HIGH POTENTIAL TO
BIODEGRADE (LOW PERSISTANCE) WITH UNACCLIMATED MICROORGANISMS FROM
ACTIVATED SLUDG E. WHEN DILUTED WITH A LARGE AMOUNT OF WATER, THIS
MATERIAL RELEASED DIRECTLY OR INDIRECTLY INTO THE ENVIRONMENT IS
NOT EXPECTED TO HAVE A SIGNIFICANT IMPACT.

Transport Information:DOT(USA) STATUS: REGULATED. CLASS 3, PACKING
GROUP II. AIR-INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO).
ICAO STATUS: REGULATED. CLASS 3, PACKING GROUP II.
SEA-INTERNATIONAL MARITIME DANGEROUS GOO DS (IMDG). IMDG STATUS:
REGULATED. CLASS 3.2, PACKING GROUP II.

SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: METHYL ISOBUTYL KETONE. SECTION 311 AND 312: FIRE HAZARD,
IMMEIDATE (ACUTE) HEALTH HAZARD.
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) INVENTORY. ANY
IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING. OSHA
CLASSIFICATION: HAZARDOUS.
State Regulatory Information:CA PROPOSITION 65: NONE KNOWN TO EASTMAN.